A Different Colour Suit for Every City - Amazing Spider-Man #11 (1964)

Doc Ock is back! After getting released from jail for good behaviour, Otto is right away back to a life of crime, kidnapping Betty and her brother Bennett Brant (say that fast 7 times!). Spider-Man has to travel to Philadelphia, grab a cheese steak and save Betty from not only Doctor Octopus but the newest and most deadly of all crime bosses, Blackie Gaxton (who?).  On top of all this we get to see Doc Ock's badass suit and Spidey trips and sprains his ankle like a dummy.